Magnesium incorporation into hydroxyapatite

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Mechanism of incorporation of zinc into hydroxyapatite.

The atomic level mechanism of incorporation of Zn(2+) into hydroxyapatite (HAp), which is a potential dopant to promote bone formation, was investigated, based on first principles total energy calculations and experimental X-ray absorption near edge structure (XANES) analyses. It was found that Zn(2+)-doped HAp tends to have a Ca-deficient chemical composition and substitutional Zn(2+) ions are...

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Zinc incorporation into hydroxylapatite.

By theoretical modeling and X-ray absorption spectroscopy, the local coordination structure of Zn incorporated into hydroxylapatite was examined. Density function theory (DFT) calculations show that Zn favors the Ca2 site over the Ca1 site, and favors tetrahedral coordination. X-ray absorption near edge structure (XANES) spectroscopy results suggest one dominant coordination environment for the...

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ژورنال

عنوان ژورنال: Biomaterials

سال: 2011

ISSN: 0142-9612

DOI: 10.1016/j.biomaterials.2010.11.017